Preheat oven to 350°F (175°C). Grease and flour two 9-inch round cake pans, or line with parchment paper circles.
In a large bowl, sift together the flour, cocoa powder, sugar, baking powder, baking soda, and salt.
In another bowl, whisk together the eggs, buttermilk, oil, and vanilla extract until smooth.
Pour the wet ingredients into the dry ingredients and stir until combined.
Slowly add the hot coffee and stir until the batter is smooth. It will be thin.
Divide the batter evenly between the prepared pans.
Bake for 30-35 minutes or until a toothpick inserted in the center comes out clean.
Cool the cakes in the pans for 10 minutes, then turn out onto wire racks to cool completely.