Preheat oven to 450°F (230°C). Line a baking sheet with foil and coat it with cooking spray.
In a large stockpot, combine water, balsamic vinegar, ¼ cup salt, bay leaf, thyme, oregano, rosemary, and minced garlic. Bring to a boil.
Add the chicken wings; return to boil and cook 15 minutes. Use a slotted spoon to remove wings and place on a cooling rack; let them dry for 15 minutes.
Meanwhile, mash garlic with a pinch of salt in a mortar and pestle until smooth.
In a large bowl, combine the garlic paste, olive oil, black pepper, and red pepper flakes. Add the wings and bread crumbs; toss to coat thoroughly.
Sprinkle ½ cup of the Parmesan over the wings. Transfer to the prepared baking sheet and sprinkle with the remaining ½ cup Parmesan.
Bake in the preheated oven 20–25 minutes, until wings are browned and crisp.
Serve hot.