Preheat oven according to cake mix directions. Grease and line two 8-inch round cake pans.
In a bowl, whisk eggs, egg yolk, hot chocolate, and oil. Add cake mix and beat until smooth.
Divide batter evenly between pans and bake 28-30 minutes or until a toothpick comes out clean.
Cool cakes for 10 minutes in pans, then transfer to a rack to cool completely. Wrap and refrigerate if making ahead.
For ganache, heat heavy cream until simmering, pour over chocolate chips, let stand 2 minutes, then stir until smooth. Cool to room temperature.
For buttercream, beat butter until fluffy, add marshmallow fluff and vanilla, mix gently, then add powdered sugar gradually.
To assemble, place first cake layer on a board, spread buttercream, drizzle ganache, top with second cake layer, repeat frosting and ganache.
Top with mini marshmallows and toast with a kitchen torch.